Thermodynamic properties of MgSiO3 ilmenite from vibrational spectra     

Anne M. Hofmeister  Eiji Ito 《Physics and Chemistry of Minerals》1992,18(7):423-432

Unpolarized infrared (IR) reflectance spectra for MgSiO₃ ilmenite taken from a single-crystal and from a densly packed polycrystalline sample possessed all eight peaks mandated by symmetry between 337 and 850 cm^?1. Polarizations were inferred from intensity differences between the two samples. IR peak positions differ by up to 250 cm^?1 from recent calculations, but on average are within 11%. Heat capacity C _p calculated from these data by using a Kieffer-type model are within the experimental uncertainty of calorimetric measurements from 170 to 700 K. Outside this range, calculated C _p is probably accurate within a few percent, based on recent results for garnets. Calculated entropy is only slightly less accurate, giving S ⁰ (298.15 K) as 54.1 ±0.5 J/ mol-K, which is 10% lower than recent estimates based on phase equilibria. The slope of the phase boundary between ilmenite and perovskite is used to predict S ⁰ (298.15 K) of perovskite as 58.7 ±1.4 J/mol-K, which is 10% lower than previous values.  相似文献   

Interaction of Fe and Fe<Subscript>3</Subscript>C with hydrogen and nitrogen at 6–20 GPa: a study by in situ X-ray diffraction     

K. D. Litasov  A. F. Shatskiy  E. Ohtani 《Geochemistry International》2016,54(10):914-921

A method of in situ X-ray diffraction at Spring-8 (Japan) was used to analyze simultaneously the hydrogen incorporation into Fe and Fe₃C, as well as to measure the relative stability of carbides, nitrides, sulfides, and hydrides of iron at pressures of 6–20 GPa and temperatures up to 1600 K. The following stability sequence of individual iron compounds was established in the studied pressure and temperature interval: FeS > FeN > FeC > FeH > Fe. A change in the unit-cell volume as compared to the known equations of state was used to estimate the hydrogen contents in carbide Fe₃C and hydride FeH_x. Data on hydride correspond to stoichiometry with x ≈ 1. Unlike iron sulfides and silicides, the solubility of hydrogen in Fe₃C seemed to be negligibly low—within measurement error. Extrapolating obtained data to pressures of the Earth’s core indicates that carbon and hydrogen are mutually incpompatible in the iron–nickel core, while nitrogen easily substitutes carbon and may be an important component of the inner core in the light of the recent models assuming the predominance of iron carbide in its composition.  相似文献   

Accumulation rate and heavy metal pollution in Osaka Bay sediments     

Eiji Matsumoto  Setsuya Yokota 《Journal of Oceanography》1978,34(3):108-115

The accumulation rates of sediment cores in Osaka Bay have been determined by using²¹⁰Pb dating technique. In the upper 10 cm²¹⁰Pb_ex contents show a constant value with depth. The accumulation rates below the homogeneous layer of sediments ranging from 0.12 to 0.61cm y^–1 (0.067–0.34 g cm^–2 y^–1) were obtained. The higher contents of Zn, Cu, Pb and Cr were observed in the upper 10 to 30 cm of sediments. Assuming that the increment of heavy metal content in sediments is due to anthropogenic origin, the amount of anthropogenic input of heavy metals into sediments were estimated to be 1,300–2,700g cm^–2 for Zn, 150 – 480 for Cu, 360 – 410 for Pb and 320 – 480 for Cr. The increment appears to start about 100 years ago. In surfical sediments most of heavy metal contents exceeded the background content, and then most part of Osaka Bay is polluted by heavy metals.  相似文献   

On Seasonal and Year to Year Variation in Flow of the Alaskan Stream in the Central North Pacific   总被引：1，自引：0，他引：1  

Hiroji Onishi  Kiyotaka Ohtani 《Journal of Oceanography》1999,55(5):597-608

The Alaskan Stream is the westward boundary current of the North Pacific subarctic gyre. In the central region of the North Pacific, the Alaskan Stream serves as a connection between the Alaskan gyre, Western subarctic gyre and Bering Sea gyre. Its volume transport is very important in estimating the magnitude of the subarctic circulation in the North Pacific. In order to clarify its seasonal and interannual variation, we conducted observations along a north-south section at 180° during June from 1990 to 1997. Moorings were deployed from 1995 to 1997. Hydrographic casts were made at intervals of 37 km to a depth of 3000 m. Moorings were set between CTD stations, with Moor1 (Moor2) at the center (southern edge) of the Alaskan Stream. Geostrophic volume transport (referred to 3000 m) revealed large interannual variability in the Alaskan Stream. Average volume transport over the 8 years was 27.5 × 10⁶ m³s^-1 with a standard deviation of 6.5 × 10⁶ m³s^-1. Maximum transport was 41.0 × 10⁶ m³s^-1 (1997) and minimum was 21.7 × 10⁶ m³s^-1 (1995). Stable westward flows were observed at Moor1 1500 m (259°, 11.7 cm s^-1) and 3000 m (240°, 3.7 cm s^-1, 1996–1997 year average). The ratio of eddy to mean kinetic energy (KE/ ) was very small (<0.6) throughout the year. A relatively weak and unstable westward flow was observed at Moor2 at 3000 m depth. Conversely, the average flow direction at Moor2 5000 m was eastward.  相似文献   

Volume transport of the Tsushima Warm Current, west of Tsugaru Strait bifurcation area     

Mitsuyo Onishi  Kiyotaka Ohtani 《Journal of Oceanography》1997,53(1):27-34

Northern and southern latitudinal transects were conducted west of Tsugaru Strait to estimate the volume transport in this area. It was found that the Tsushima Warm Current is the northward volume transport across the southern transect and the Northward Current is the northward volume transport across the northern transect. The current in Tsugaru Strait,viz. the Tsugaru Warm Current, is the flow remaining when the Northward Current is subtracted from the Tsushima Warm Current. Both CTD transects covered from near-shore to west of the subarctic front, and observed depths were from the surface to the bottom or to 1000-1500 m depth. Our estimations indicate that large interannual variations of volume transport occur, relative to the seasonal ones, with interannual variations sometimes exceeding seasonal variations in the Tsushima Warm Current and the Northward Current. The Tsugaru Warm Current has near-steady transport. Fluctuations in the Tsushima Warm Current are thus transmitted to the Northward Current. Further, our results revealed seasonal variations in the flow: the baloclinic structure became deeper in April and the current axis tended to shift in a near-shore direction in October. Therefore, previous studies, which had shallow reference levels and lacked nearshore stations, may have underestimated the transport and excessive seasonal variations.  相似文献   

Diagenetic behavior of manganese in Tokyo Bay sediment     

Masahiro Sakata  Yasushi Kitano  Eiji Matsumoto 《Journal of Oceanography》1981,37(4):212-217

To understand the behavior of manganese in diagenetic processes in sediments of an enclosed bay which is similar to those of an estuary, chemical analyses have been carried out on both sediment and interstitial water of a core sample collected from Tokyo Bay. The results suggest that redistribution of manganese takes place within the sediment as a result of the dissolution of buried manganese oxides and hydroxides under reducing condition, the downward diffusion of Mn²⁺ through the interstitial water toward lower layers and then the precipitation of carbonate. The carbonate formed in the sediment contains managanese carbonate probably as a solid solution between calcitic calcium carbonate and manganese carbonate.  相似文献   

The distribution of suspended particles in the Southern Beaufort Sea     

Eiji Matsumoto  C. S. Wong 《Journal of Oceanography》1977,33(4):227-233

The Mackenzie River estuary serves as an avenue for suspended particles to pass seaward. The horizontal distribution of surface suspended particles is compartible with the distribution of low-salinity surface waters. The water structure in the shelf area is highly stratified in summer due to a thin upper layer of low-salinity which has a high concentration of suspended particles. The concentration of suspended particles decreases with depth, but near the bottom a turbid layer had often been observed. It is likely that bottom current energy high enough to erode and maintain in suspension the bottom sediments below 15m in diameter does occur over this shelf area.  相似文献   

Carbon dioxide in surface seawaters of the Seto Inland Sea,Japan     

Eiji Ohtaki  Eiji Yamashita  Fukuichi Fujiwara 《Journal of Oceanography》1993,49(3):295-303

Observations were made of time variations of carbon dioxide in seawater, pCO₂, and in the atmosphere, PCO₂, in the Seto Inland Sea of Japan. The pCO₂ data showed well defined diurnal variation; high values at nighttime and low values during daylight hours. The pCO₂ correlated negatively with dissolved oxygen. These results denote that the diurnal variation of pCO₂ is associated with effects of photoplankton's activity in seawater. The pCO₂ measured in the Seto Inland Sea showed higher values than the PCO₂ during June to November, denoting transport of carbon dioxide from the sea surface to the atmosphere, and lower values during December to May, denoting transport of carbon dioxide from the atmosphere to the sea surface. The exchange rates of carbon dioxide were calculated using working formula given by Andriéet al. (1986). The results showed that the Seto Inland Sea gained carbon dioxide of 1.0 m-mol m^–2 d^–1 from the atmosphere in March and lost 1.7 m-mol m^–2 d^–1 to the atmosphere in August.  相似文献   

Accounting for spatial correlation in tsunami evacuation destination choice: a case study of the Great East Japan Earthquake     

Giancarlos Troncoso Parady  Eiji Hato 《Natural Hazards》2016,80(2):797-810

  相似文献   

Transformation textures,mechanisms of formation of high‐pressure minerals in shock melt veins of L6 chondrites,and pressure‐temperature conditions of the shock events     

Shin Ozawa  Eiji Ohtani  Masaaki Miyahara  Akio Suzuki  Makoto Kimura  Yoshinori Ito 《Meteoritics & planetary science》2009,44(11):1771-1786

Abstract— The high‐pressure polymorphs of olivine, pyroxene, and plagioclase in or adjacent to shock melt veins (SMVs) in two L6 chondrites (Sahara 98222 and Yamato 74445) were investigated to clarify the related transformation mechanisms and to estimate the pressure‐temperature conditions of the shock events. Wadsleyite and jadeite were identified in Sahara 98222. Wadsleyite, ringwoodite, majorite, akimotoite, jadeite, and lingunite (NaAlSi₃O₈‐hollandite) were identified in Yamato 74445. Wadsleyite nucleated along the grain boundaries and fractures of original olivine. The nucleation and growth of ringwoodite occurred along the grain boundaries of original olivine, and as intracrystalline ringwoodite lamellae within original olivine. The nucleation and growth of majorite took place along the grain boundaries or fractures in original enstatite. Jadeite‐containing assemblages have complicated textures containing “particle‐like,” “stringer‐like,” and “polycrystalline‐like” phases. Coexistence of lingunite and jadeite‐containing assemblages shows a vein‐like texture. We discuss these transformation mechanisms based on our textural observations and chemical composition analyses. The shock pressure and temperature conditions in the SMVs of these meteorites were also estimated based on the mineral assemblages in the SMVs and in comparison with static high‐pressure experimental results as follows: 13–16 GPa, >1900 °C for Sahara 98222 and 17–24 GPa, >2100 °C for Yamato 74445.  相似文献